The atoms in a crystal of diamond are bonded into one giant molecule. Each carbon atom is covalently bonded to four other carbon atoms, and so each carbon atom has four nearest neighbors. That is, its coordination number is 4. When just four bonding pairs of electrons surround an atom, they are arranged tetrahedrally. This is the case with diamond. All outer electrons of the carbon atoms are involved in the formation of covalent bonds. There is no possibility of delocalized or mobile electrons. As a consequence, diamond cannot conduct electricity.
Diamond burns when heated in air to 900°C; in an inert atmosphere it reverts to graphite slowly at 1000°C, rapidly at 1700°C.
Natural diamonds occur in some ancient volcanic "pipes," such as those in South Africa, Tanzania, and in the United States at Murfreesboro, Arkansas, and have been recovered from the ocean floor off the Cape of Good Hope. Microscopic diamonds have also been found in some meteorites.
Diamonds in meteoritesDiamonds have been found inside meteorites. Some of these diamonds were formed by shock pressure during violent impacts between asteroids in the asteroid belt. Shock-formed diamonds tend to be very cracked and measure one or two millimeters in size.
Another type of diamond in meteorites occurs as tiny crystals measuring only a few nanometers across. They contain an isotope of xenon that is very rare on Earth but common in supernova remnants, suggesting that this is where they formed. Nanodiamonds are also surprisingly abundant, making up about 3 per cent of the carbon in meteorites in which they occur. If the same is true of carbon in interstellar space, just a gram of the dust and gas in an interstellar cloud could contain as many as 10,000 trillion nanodiamonds.
Black diamondsSo-called black diamonds, or carbonado, may be also have come from space. Black diamonds are only found in Brazil and the Central African Republic and, unlike other diamonds, are made of millions of diamond crystals stuck together. They are porous, too, which is puzzling because it would have been difficult for gas to become trapped in rocks at the depths at which terrestrial diamonds were formed – about 200 km below the surface. In a paper published in 2007, Stephen Haggerty, a geologist at Florida International University, proposes that the black diamonds arrived from space in a kilometer-sized rock between 2.6 billion and 3.8 billion years ago. At that time, South America and Africa were one land mass, which could account for the diamonds showing up on two continents today.
Related category INORGANIC CHEMISTRY
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