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molybdenum (Mo)





molybdenite
Molybdenite. Photo from MII, courtesy of the Smithsonian Institution
A silver-white metallic element in group VIB of the periodic table; a transition element. It is obtained commercially by roasting molybdenite in air and reducing the oxide formed with carbon in an electric furnace or by the thermite process to give ferromolybdenum; a smaller amount of molybdenum is recovered from wulfenite and as a by-product or co-product from copper mining.

Because of its high melting point, it is used to support the filament in electric lamps and for furnace heating elements. It also finds use in corrosion-resistant, high-temperature steels and alloys.

Molybdenum is unreactive, but forms various covalent compounds. Some are used as industrial catalysts. Molybdenum is a vital trace element in plants and a catalyst in bacterial nitrogen fixation.


Discovery of molybdenum

Molybdenum was discovered by the Swedish scientist Peter Hjelm in 1781, three years after his compatriot Carl William Scheele proposed that a previously unknown element could be found in the mineral molybdenite. While studying molybdenite in 1778, Scheele at first thought he had identified lead in it (molybdenite is named after the Greek molybdos for lead). But Sheele's investigations led him to conclude that the did not contain lead, but a new element, molybdenum which he named after the mineral. (The mineral scheelite (Ca(WO4,MoO4), calcium tungstate-molybdate) was later named in Scheele's honor.)


atomic number 42
relative atomic mass 95.9
relative density 10.2 (at 20°C)
melting point 2,610°C (4,730°F)
boiling point 5,560°C (10,040°F)


Related category

   • INORGANIC CHEMISTRY