transition element
A metallic element that has an incomplete
inner shell. Transition elements occupy the
short groups in the periodic table
– i.e., groups IB through VIIB and group VIII – in which the
d-orbitals are being filled. In
general the transition elements are dense, hard, and of high melting
point. Their electronic structures, with many loosely-bound unpaired
d electrons, account for their
properties: they exhibit many different valence
states, form stable ligand complexes, are
mostly colored and paramagnetic, and
are generally good catalysts. They form
many stable organometallic compounds
and carbonyls (compounds in which
carbon monoxide, CO, acts as a ligand) with specially stable "push-pull"
bonding. The second and third row transition elements are less reactive
than the first row, and stable in higher valence states. Many transition
elements are technologically important.
Related categories
ATOMIC
AND NUCLEAR PHYSICS INORGANIC
CHEMISTRY
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