Polymerization, which requires that each monomer has two or more functional groups capable of linkage, takes place by two processes: condensation with elimination of small molecules, or simple addition. Catalysis is usually required, or the use of an initiator to start a chain reaction of free radicals.
Polymers made up of a single type of monomer are called homopolymers. If more than one kind of monomer is used, the result is a copolymer or heteropolymer. In the case of copolymers the different monomer units may alternate, following some other repeating (periodic) or statistical sequence, or be arranged at random. Under special conditions it is possible to form stereoregular polymers, with the groups regularly oriented in space; these have useful properties. Linear polymers may form crystals in which the chains are folded sinuously, or they may form an amorphous tangle. Stretching may orient and extend the chains, giving increased tensile strength useful in synthetic fibers. Some cross-linking between the chains produces elasticity; a high-degree of cross-linking yields a hard, infusible product (a thermosetting plastic).
Related categories INORGANIC CHEMISTRY
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