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colloid





colloidal crystal
A diffraction pattern from a binary colloidal alloy crystal
Also known as a colloidal solution or colloidal dispersion, a system in which two (or more) substances are uniformly mixed so that one is extremely finely dispersed throughout the other. A colloid may be viewed intuitively as a halway stage between a suspension and a solution. Familiar examples are milk, butter, paint, and ink.

In a colloid there two or more phases, with one (the dispersed phase) distributed in the other (the continuous phase). At least one of the phases has small dimensions, in the range between 1 nanometer and 1 micrometer (10-9–10-6 m). Dimension, rather than the nature of the material, is characteristic. In this size range, the surface area of the particle is large with respect to its volume so that unusual phenomena occur, e.g., the particles do not settle out of the suspension by gravity and are small enough to pass through filter membranes. Another notable property of colloids is light dispersion: it is due to the colloidal particles in the atmosphere that the sky is blue in the daytime and the sunset red.

Macromolecules (proteins and other high polymers) are at the lower limit of the colloidal particle range; the upper limit is usually taken to be the point at which the particles can be resolved in an optical microscope.

Colloidal particles may be gaseous, liquid, or solid, and occur in various types of suspensions:
  • Sols – dispersions of small solid particles in a liquid
  • Emulsions – colloidal systems in which the dispersed and continuous phases are both liquids
  • Gels – colloids in which both dispersed and continuous phases have a three-dimensional network throughout the material
  • Aerosols – colloidal dispersions of liquid or solid particles in a gas
  • Foams – dispersions of gases in liquids or solids
Of special interest to studies of the origin of life are the colloidal entities known as coacervates.


Related entries

   • Brownian motion
   • electrophoresis


Related categories

   • STATES OF MATTER
   • PHYSICAL CHEMISTRY