acetic acid

acetic acid

Ball-and-stick model of the acetic acid molecule. Carbon atoms = black, hydrogen = white, oxygen = red.

Acetic acid, also known as ethanoic acid, CH3COOH, is the simplest carboxylic acid. It is a pungent, colorless, corrosive liquid. It is the acid found in vinegar and is often used as a reagent in making acetates and in biosynthesis. It is also used in the preparation of pharmaceuticals, and in industry. Pure ("glacial") acetic acid solidifies to ice-like crystals and is corrosive. Relative density is 1.049, melting point 16.6°C, boiling point 117.9°C.


Acetic acid is produced industrially by the liquid-phase oxidation of acetaldehyde (ethanal) at 60°C by oxygen or air under pressure in the presence of manganese (II) ethanoate (the latter preventing the formation of perethanoic acid). Another important route is the liquid-phase oxidation of butane by air at 50 atm. and 150–250°C in the presence of a metal ethanoate. On a small scale it is produced by bacterial action on alcohol, yielding vinegar.


Chemistry of acetic acid

Acetic acid is a very stable substances – it resists the action of reducing and oxidizing agents and does not readily decompose when heated. For these reasons it is a useful solvent for organic substances. Acetic acid has the usual properties of acids, such as reacting with bases to form salts. Although there are four hydrogen atoms in a molecule of acetic acid, only the one in the carboxyl (–COOH) group can be replaced by a metal. The salts of acetic acid are called acetates (or ethanoates), thus sodium acetate is obtained when acetic acid is neutralized by sodium hydroxide. Acetic acid also reacts with alcohols to form a class of compounds called esters. In certain ways the esters are comparable with salts in inorganic chemistry.


Acetic acid is a raw material for the manufacture on an industrial scale of a great variety of materials. It is used in the manufacture of various plastic substances such as cellulose acetate, vinyl acetate, and acetate fibers. Insoluble iron (III) acetate and aluminum acetate are deposited in cotton fabrics before they are dyed. These substances, which are known as mordants, fix dyestuffs into the cotton fibers. Acetic acid is also used in the manufacture of drugs (e.g. aspirin) and of white lead of paint.