Explosives are substances capable of very rapid combustion (or other exothermic reaction) to produce hot gases whose rapid expansion is accompanied by a high velocity shock wave, shattering nearby objects. The detonation travels 1,000 times faster than a flame.
The earliest known explosive was gunpowder, invented in China in the 10th century AD, and in the West by Roger Bacon (1242).
Explosives are classified as primary explosives, which explode at once on ignition, and are used as detonators; and high explosives, which if ignited at first merely burn, but explode if detonated by primary explosion. The division is not rigid. Military high explosives are usually mixtures of organic nitrates, TNT, RDX, picric acid, and PETN, which are self-oxidizing. Commercial blasting explosives are less-powerful mixtures of combustible and explosive substances; they include dynamite (containing nitroglycerin, ammonium nitrate, and sometimes nitrocellulose), ammonals (ammonium nitrate + aluminum), and Sprengel explosives (an oxidizing agent mixed with a liquid fuel such as nitrobenzene just before use). Obsolete explosives include the dangerous chlorates and perchlorates, and the uneconomical liquid oxygen explosives (LOX). Explosives which do ignite firedamp are termed "permissible," and may be used in coal mines. Propellants for guns and rockets are like explosives, but burn fast rather than detonating. See propellant.
History of explosivesOne day in 1913 when the Canadian Northern Railway's tunnel was being built at Yale, British Columbia, an engineer made a mistake in the strength of a dynamite blast that he had ordered. Instead of merely breaking loose a calculated amount of rock it knocked the entire face of a cliff into the Fraser River. It was the time when the salmon were coming upstream to breed. The rock caused a dam 9 feet high on the river, and the salmon could not jump it because the water was coming over the top with the strength of a fire-hose. It is estimated that millions of salmon died because of the engineer's mistake.
Four years later, on 6th December at Halifax, Nova Scotia, a French munitions ship blew up in the harbour, destroyed a large part of the city and killed 1,600 people – one of the worst explosions in history.
These stories illustrate the two main uses of explosives: in the first they were being used to help man's progress, and in the second they were intended to be used as a weapon or war; but both also show that human errors (and these were made by experts) can cause fantastic harm and devastation.
The conclusion is obvious: while explosives are one of the most important inventions of mankind and have changed the whole course of history, they are also one of the most dangerous.
Handling of explosivesGovernments are quite aware of the danger of explosives, and in Britain the Explosives Acts of 1875 and 1923 limit the making of explosives to special factories. Buildings have to be built away from each other and some have to be surrounded by a protective embankment. A typical factory is divided into 'non-danger' and 'danger' areas. The manufacture of nitric and sulfuric acids takes place in the non-danger area. The explosives are made and packed in the danger area.
The main danger is ignition by spark, friction, or impact. Naked lights, steel tools, or anything that might produce a spark or flame are excluded from the building. Each factory had a 'clean' floor, and workers can only walk on it in specially cleaned shoes.
Propellants and high explosives
Gunpowder, the oldest and easiest explosive to make, can be ignited by a spark or a flame, but with the improved types used today other methods are employed. Propellants can be set off by a flame coming either from a small quantity of explosive held in a cap (when you pull the trigger of a gun the cartridge cap is hit sharply) or from a gunpowder igniter. This consists of a thin wire embedded in gunpowder: an electric current is passed through the wire which heats it so that it sets light to the powder. The most commonly used explosive is T N T (Trinitrotoluene). Nearly all high explosives are made by treating some substance containing carbon with nitric acid.
High explosives must be set off by a violent shock, as they will just burn without exploding if a flame is applied. Detonators containing an explosive charge which can be easily set off, such as cyclonite, tetryl or mercuric fulminate, are used for this purpose. Some artillery shells contain high explosive. A detonator is fitted on the nose of the shell so that when the shell hits its target the high explosive is set off, causing widespread damage.
Developments in manufactureThe first true gunpowder is believed to have been made by the English Friar Roger Bacon in the 13th century, although it is known that the Chinese and the Arabs had produced similar mixtures several centuries earlier. Soon after the invention of gunpowder, its military uses were appreciated and new weapons were made. From that time onwards explosives had a great influence on the history of the world.
Gunpowder was originally made in private homes, but this habit was so dangerous that its manufacture was limited to special places, such as the Tower of London, in 1461. In the 17th century gunpowder became valued as a blasting agent; it was used for rock blasting in Hungary, in the tin mines of Cornwall, and in an engineering project in Switzerland.
A big break-though came in 1846 when the German chemist Schonbein made 'guncotton' by treating cotton fibre with strong nitric and sulfuric acids. The more modern method of making a similar explosive is to use paper or wood-shavings instead of cotton.
A year later, in 1847, an Italian, Ascanio Sobrero, invented one of the most famous of all explosives, nitro-glycerine. He dipped glycerine into nitric and sulfuric acids and by this means made an explosive substance that produced 12,000 times its own volume of gas when exploded. However, as nitroglycerine could be set off by rough handling, its use was dangerous and restricted.
But in 1866 the great Swedish scientist Alfred Nobel, after whom the Nobel Prize is called, discovered that if he mixed nitro-glycerine with a sandy substance called kieselguhr its texture became rather like that of cheese and it could be handled with greater ease and safety. This mixture became known as dynamite. He also found that if guncotton was mixed with nitro-glycerine it formed a stiff jelly. This became known as blasting gelatine and is widely used today in quarrying.
Uses of explosivesApart from their obvious uses in warfare, explosives are of great service to man. They can send rockets soaring upwards into space; they can also help man bore down into the earth in search of coal and other materials. Mining and quarrying would be very laborious jobs without them. It is ironical that though explosives have probably caused more fires than any other substances, they can also be used for extinguishing fires in oil wells. This is done by 'blowing out' the fire with an explosive blast.
High explosive for blasting rock
Explosives are set off by detonators
The nature of an explosion
What are explosives made of?Because explosives produce a large volume of gas by immediate combustion it is obvious that they must all contain an ingredient which yields the necessary oxygen – without which nothing can burn – and an ingredient which combines with the oxygen. One of the simplest explosives is gunpowder, which is a mixture of potassium nitrate (saltpetre), charcoal, and sulphur. When burnt, it gives off about 4,000 times its own volume of gas. The charcoal and sulfur burn in the oxygen given off by the saltpetre and the action is very rapid. A more powerful explosive – guncotton – which was invented by the German scientist Christian Schonbein in 1846 is made by treating cotton fibre with strong nitric and sulfuric acids. A piece of fibre treated like this would burn swiftly but safely if lit. If struck, however, it would explode with great violence.
Related category INDUSTRIAL CHEMISTRY
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